Inorganic elements

Group VIB (chalcogens)

Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Oxygen (O) 8 [He] 2s22p4 -1/2, -1, -2 15.9994
Sulfur (S) 16 [Ne] 3s23p4 +6, +4, +3, -2 32.064
Selenium (Se) 34 [Ar] 3d104S24p4 -2, +4 , +6 78.96
Tellurium (Te) 52 [Kr] 4d105s25p4 -2, +4, +6 127.60
Polonium (Po) 84 [Xe] 4f145d106s26p4 +2, +4, +6 210*

 

Oxygen (group VIB, chalcogens)
Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Oxygen (O) 8 [He] 2s22p4 -1/2, -1, -2 15.9994

Compounds of oxygen

Peroxides: O22- (in the peroxyl group, the oxidation state of oxygen is - 1)

Hydrogen peroxide: H2O2
sodium peroxide: Na2O2

Superoxides: O2- (in the superoxyl group, the oxidation state of oxygen is - 1/2)

Peroxy acids: Acids in which an acidic -OH group has been replaced by an -OOH group.  E.g. CH3C(=O)OOH peroxyacetic acid, PhS(=O)2OOH benzeneperoxysulfonic acid.

 

Sulfur
Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Sulfur (S) 16 [Ne] 3s23p4 +6, +4, +3, -2 32.064

Compounds of sulfur

Sulfates: SO42- = ion sulfate. Examples: Sodium sulfate (Glauber's salt): Na2SO4.

Peroxydisulfuric acid: H2S2O8, is an extremely powerful oxidizing agent. The oxidation reaction is slow but can be catalyzed by silver ions.

Dithionous acid, disodium salt (synomims: Sodium dithionite; sodium hydrosulfite, Sodium sulfoxylate; Virtex L; Reductone; Hydrolin; Vatrolite )

Sulfurous acid (H2SO3) is the hydrated form of sulfur dioxide (SO2), a colorless gas with a characteristic choking odor. It is a weak acid which can dissociate into bisulfite (HSO3-) and sulfite (SO32-) ions.

H2O (l) + SO2(g) = H2SO3 = HSO3- + H+
HSO3- = SO32- + H+

In acidic solution, the equilibria are shifted to form sulfurous acid, resulting in the evolution of SO2 gas. Sulfite ion is readily oxidized to sulfate, e.g. by prolonged exposure to atmospheric oxygen or by permanganate. The decolorization of permanganate solutions serves as a convenient test for sulfur dioxide. The sulfites of Na+, K+, and NH4+ are soluble in water. Most other sulfites are insoluble in water. However, due to the basic nature of SO32-, all sulfites dissolve in acidic solution.

 

 

 

Selenium
Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Selenium (Se) 34 [Ar] 3d104S24p4 -2, +4 , +6 78.96

 

Tellurium
Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Tellurium (Te) 52 [Kr] 4d105s25p4 -2, +4, +6 127.60

 

Polonium
Atomic Number
Electron configuration
Oxidation numbers
Atomic Weight
Polonium (Po) 84 [Xe] 4f145d106s26p4 +2, +4, +6 210*